Saturday, May 16, 2020
Enthalpy Change for a Specific Amount of Reactant
Here is how to determineà the change in enthalpy of a chemical reaction with a given amount of reactant.à You may wish to review the laws of thermochemistry and endothermic and exothermic reactionsââ¬â¹ before you begin. Problem: For the decomposition of hydrogen peroxide, it is known that:H2O2(l) ââ â H2O(l) 1/2 O2(g); ÃâH -98.2 kJUsing this information, determine ÃâH for the reaction:2 H2O(l) O2(g) ââ â 2 H2O2(l) Solution: When looking at the second equation, we see it is double the first reaction and in the opposite direction. First, change the direction of the first equation.à When the direction of the reaction is changed, the sign on ÃâH changes for the reaction H 2O2(l) ââ â H2O(l) 1/2 O2(g); ÃâH -98.2 kJ becomes H2O(l) 1/2 O2(g) ââ â H2O2(l); ÃâH 98.2 kJ Second, multiply this reaction by 2.à When multiplying a reaction by a constant, the ÃâH is multiplied by the same constant.2 H2O(l) O2(g) ââ â 2 H2O2(l); ÃâH 196.4 kJ Answer: ÃâH 196.4 kJ for the reaction: 2 H2O(l) O2(g) ââ â 2 H2O2(l)
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